- As of mid-September 2021, Mack is incarcerated in the U.S. federal prison system, at Federal Correctional Institution (FCI) Dublin, a low-security prison for female inmates in Dublin, California, near San Francisco. FCI Dublin is also where Felicity Huffman and Lori Loughlin each served short sentences in relation to a college admissions bribery scandal. Mack's projected release date is December 15, 2023; however, she was released on July 5, 2023.
- An old autographed head shot from when she was a child still lies framed on the wall of a Taco Bell restaurant across the street from Warner Bros. Studios on Olive Ave. in Burbank, CA.
- Learned to knit from co-star Annette O'Toole.
- Had her hair cut short just before the third season of Smallville (2001) went into production. After shooting the season opener, producers insisted she wear a hairpiece until her hair grew longer. They felt her haircut did not suit the character of Chloe Sullivan.
- Her father is an opera singer.
- Was listed among the 50 Sexiest Women in "Femme Fatales" (January/February 2005) magazine.
- The Mack family moved back to the US from Germany when she was two years old.
- Attended the 2003 San Diego International Comic-Con with co-star Sam Jones III to promote the third season of Smallville (2001).
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